Copper(I)-Catalyzed Synthesis of 1,4-Disubstituted 1,2,3-Triazoles from Azidoformates and Aryl Terminal Alkynes
收藏NIAID Data Ecosystem2026-03-10 收录
下载链接：
https://figshare.com/articles/dataset/Copper_I_-Catalyzed_Synthesis_of_1_4-Disubstituted_1_2_3-Triazoles_from_Azidoformates_and_Aryl_Terminal_Alkynes/6089774
下载链接
链接失效反馈官方服务：
资源简介：
The copper(I)-catalyzed azide–alkyne
cycloaddition reaction
has been extensively studied and widely applied in organic synthesis.
However, the formation of 1,2,3-triazoles with electron-deficient
azide has been a challenging problem. In this report, we have demonstrated
the formation of regioselective 1,4-disubstituted 1,2,3-triazoles
from various types of aryl terminal alkynes and azidoformates, which
are electron-deficient azides, using a commercialized [Cu(CH3CN)4]PF6 copper(I) catalyst under mild conditions.
创建时间：
2018-04-04
