Replication data of Buchmeiser group for: "Cationic Tungsten Imido Alkylidene...

B2FIND2026-03-19 收录

有机金属化学

过渡金属配合物催化

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https://b2find.eudat.eu/dataset/82c5f292-a105-5795-939f-350debddd214 数据链接链接失效反馈

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Neutral and cationic tungsten imido alkylidene complexes of the general formulas W(NtBu)(CHR1)(OR2)Cl(NHC),W(N-2,6-bis(2,4,6-tri-iPr-C6H4)phenyl)(CHR1)Cl2(NHC),...

Transition-Metal-Substituted Dichlorobismuthanes as Starting Materials for Novel Bismuth−Transition-Metal Clusters †

金属簇合物合成

有机金属化学

The reaction of [{Cp(CO)2Fe}BiCl2] (1a) with [Co(CO)4]- leads to the formation of the first heteroleptic substituted bismuthane, [(μ3-Bi){Co(CO)4}2{Fe(CO)2Cp}] (2). When the “open” complex 2 is irradi

NIAID Data Ecosystem90

Reductive Elimination from Phosphine-Ligated Alkylpalladium(II) Amido Complexes To Form sp 3 Carbon–Nitrogen Bonds

有机金属化学

化学键形成机制

We report the formation of phosphine-ligated alkylpalladium(II) amido complexes that undergo reductive elimination to form alkyl-nitrogen bonds and a combined experimental and computational investiga

NIAID Data Ecosystem60

New Ruthenium(II) Complexes Bearing N - Heterocyclic Carbenes

N-杂环卡宾配合物

有机金属化学

N-heterocyclic carbene complexes of ruthenium(II), [CpRu(L*)2Cl] (2) and [CpRu(CO)(L*)Cl] (3) (Cp = η5-C5H5; L* = 1,3-dicyclohexyl-imidazolin-2-ylidene), have been obtained in high yields by reaction

NIAID Data Ecosystem50

Seven-Membered Cyclic Dialkylstannylene and -Plumbylene Compounds Stabilized by Agostic-type B−H···E Interactions [E = Sn, Pb]

有机金属化学

化合物稳定性

The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn

NIAID Data Ecosystem70

Adding a New Dimension to the Investigation of Platinum-Mediated Arene C−H Activation Reactions Using 2D NMR Exchange Spectroscopy. Dynamics of Pt(II) Phenyl/Benzene Site Exchange

有机金属化学

配体交换动力学

Protonation of (N−N)PtPh2 (1; N−N = diimine ArNCMe−CMeNAr with Ar = 2,6-Me2C6H3 (a), 2,4,6-Me3C6H2 (b), 4-Br-2,6-Me2C6H2 (c), 3,5-Me2C6H3 (d), and 4-CF3C6H4 (e)) in the presence of MeCN at ambient t

NIAID Data Ecosystem60

Replication data of Buchmeiser group for: "Cationic Tungsten Imido Alkylidene...

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