Preparation, Structure, Bonding, and Preliminary Reactivity of a Six-Coordinate d4 Osmium–Boryl Complex
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https://figshare.com/articles/dataset/Preparation_Structure_Bonding_and_Preliminary_Reactivity_of_a_Six_Coordinate_d_sup_4_sup_Osmium_Boryl_Complex/2506933
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The d4 ML6 bis-boryl complex OsH(Bcat)2Cl(PiPr3)2 (Bcat = catecholborate) has been prepared by the reaction of OsH2Cl2(PiPr3)2 with HBcat, via the monoboryl intermediate OsH2(Bcat)Cl(PiPr3)2, and its structure determined by X-ray diffraction analysis. The Os–B bonds and the stability and disposition of the boryl ligands have been analyzed by DFT calculations. The bis-boryl complex loses HBcat to give Os(Bcat)Cl(CO)2(PiPr3)2, under a CO atmosphere.
创建时间：
2016-02-20
