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A New Bimetallic Ferrimagnet ([Mn<sub>2</sub><sup>II</sup>(H<sub>2</sub>O)<sub>2</sub>(CH<sub>3</sub>COO)][Mo<sup>V</sup>(CN)<sub>8</sub>]·2H<sub>2</sub>O)<sub>n</sub> and Its Antiferromagnetic Analogue ([Mn<sub>2</sub><sup>II</sup>(H<sub>2</sub>O)<sub>3</sub>Cl][Mo<sup>V</sup>(CN)<sub>8</sub>]·4H<

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The reaction between Cs3[Mo(CN)8]·2H2O and MnCl2·4H2O gives two new cyano-bridged bimetallic compounds of ([Mn2II(H2O)2(CH3COO)][MoV(CN)8]·2H2O)n (1) and ([Mn2II(H2O)3Cl][MoV(CN)8]·4H2O)n (2) in different conditions. The magnetic behaviors of these complexes have been investigated, indicating that 1 is a ferrimagnet with an ordering temperature of about 6 K and that for 2 there is antiferromagnetic coupling between the paramagnetic ions in the system.

创建时间:
2008-10-01
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