Heterometallic Co<sup>III</sup>–Gd<sup>III</sup> Clusters as Magnetic Refrigerants
收藏NIAID Data Ecosystem2026-03-09 收录
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Two heterometallic CoIII–GdIII nanomagnets (Co2Gd6 and Co2Gd9) with defective dicubane-like cores were isolated from the same set of reactants by varying the reaction conditions. These are the first examples of cobalt(III)–gadolinium(III) phosphonate compounds and a rare class of compounds with large 4f ratio among the reported 3d–4f complexes. Magnetic studies reveal large magnetic entropy changes for both complexes (−ΔSm = 27.81 and 33.07 J kg–1 K–1, respectively at 3 K and 7 T).
创建时间：
2016-08-31
