Oligosilanylated Antimony Compounds
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https://figshare.com/articles/dataset/Oligosilanylated_Antimony_Compounds/2050086
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资源简介：
By reactions of magnesium oligosilanides
with SbCl3,
a number of oligosilanylated antimony compounds were obtained. When
oligosilanyl dianions were used, either the expected cyclic disilylated
halostibine was obtained or alternatively the formation of a distibine
was observed. Deliberate formation of the distibine from the disilylated
halostibine was achieved by reductive coupling with C8K.
Computational studies of Sb–Sb bond energies, barriers of pyramidal
inversion at Sb, and the conformational behavior of distibines provided
insight for the understanding of the spectroscopic properties.
创建时间：
2015-12-17
