Catalytic Desymmetrization of meso-Aziridines with Benzofuran-2(3H)‑Ones Employing a Simple In Situ-Generated Magnesium Catalyst
收藏Figshare2016-02-12 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Catalytic_Desymmetrization_of_i_meso_i_Aziridines_with_Benzofuran_2_3_i_H_i_Ones_Employing_a_Simple_In_Situ_Generated_Magnesium_Catalyst/2102827
下载链接
链接失效反馈官方服务：
资源简介：
The first example of catalytic desymmetrization of meso-aziridines with benzofuran-2(3H)-ones is realized by employing a magnesium catalyst utilizing BINOL as a simple and commercially available chiral ligand. Both of the enantiomers of the ring-opening product could be easily accessed by employing (R)- or (S)-BINOL as chiral ligand, respectively. A variety of enantioenriched 3,3-disubstituted benzofuran-2(3H)-ones containing multiple linear continuous stereocenters were obtained with moderate to good yields, diastereo- and enantioselectivities.
创建时间：
2016-02-12
