Regioselectivity of the C‑Metalation of 6‑Furylpurine: Importance of Directing Effects
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https://figshare.com/articles/dataset/Regioselectivity_of_the_C_Metalation_of_6_Furylpurine_Importance_of_Directing_Effects/2170213
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资源简介：
We report the C-metalation of 6-furylpurine
with Pt2+, Pd2+, and Hg2+. The ligand
binds the metal ions in a bidentate fashion, involving the N7 purine
atom and one of the furyl carbon atoms. The regioselectivity is determined
by the metal ion. Pt2+ and Pd2+ coordinate the
furyl moiety in its β position and Hg2+ in its electronically
preferred α position.
创建时间：
2016-02-13
