Diastereoselective <i>dl</i>-Hydrocoupling of Benzalacetones by Electroreduction
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Electroreduction of benzalacetones with an undivided cell in Et4NOTs/acetonitrile gave cyclized dl-hydrodimers as mixtures of two diastereomers. The hydrodimerization proceeded stereoselectively to afford linear dl-hydrodimers, and the following cyclization led to two thermodynamically stable diasteromers of cyclopentanols.
创建时间：
2016-05-07
