Regio- and Stereoselective Addition of HO/OOH to Allylic Alcohols
收藏Figshare2020-07-27 更新2026-04-28 收录
下载链接：
https://figshare.com/articles/dataset/Regio-_and_Stereoselective_Addition_of_HO_OOH_to_Allylic_Alcohols/12721624
下载链接
链接失效反馈官方服务：
资源简介：
A range of allylic alcohols are shown to readily react with ethereal H2O2 in the presence of catalytic amounts of Na2MoO4-gly or MoO2(acac)2, affording the CC trans hydroxylation–hydroperoxylation products in good yields with high regio- and stereoselectivity. Use of enantiomers of cyclic substrates resulted in corresponding enantiopure diol-tert-hydroperoxides. The possibility of further conversion of the diol-tert-hydroperoxides into triols or linear building blocks with an isolated tert-peroxy group containing a quaternary center is also exemplified.
创建时间：
2020-07-27
