P(NMe<sub>2</sub>)<sub>3</sub>‑Mediated Aziridination of Imines with α‑Ketoesters for Synthesis of Aziridine-2-carboxylates
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Aziridination of N-sulfonyl imines with α-ketoesters in the presence of P(NMe2)3 is reported. Adducts derived from trivalent phosphorus reagents and α-ketoesters are effectively intercepted by imines, affording a range of aziridine-2-carboxylates. The diastereoselectivity of the reaction depends on steric hindrance from substituents on the substrates.
创建时间：
2016-12-21
