Heterometallic CoIII–GdIII Clusters as Magnetic Refrigerants
收藏Figshare2016-08-31 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Heterometallic_Co_sup_III_sup_Gd_sup_III_sup_Clusters_as_Magnetic_Refrigerants/3566688
下载链接
链接失效反馈官方服务：
资源简介：
Two heterometallic CoIII–GdIII nanomagnets (Co2Gd6 and Co2Gd9) with defective dicubane-like cores were isolated from the same set of reactants by varying the reaction conditions. These are the first examples of cobalt(III)–gadolinium(III) phosphonate compounds and a rare class of compounds with large 4f ratio among the reported 3d–4f complexes. Magnetic studies reveal large magnetic entropy changes for both complexes (−ΔSm = 27.81 and 33.07 J kg–1 K–1, respectively at 3 K and 7 T).
创建时间：
2016-08-31
