Three Giant Lanthanide Clusters Ln<sub>37</sub> (Ln = Gd, Tb, and Eu) Featuring A Double-Cage Structure
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Three homometallic high-nuclearity clusters, formulated as [(CO3)2@Ln37(LH3)8(CH3COO)21(CO3)12(μ3-OH)41(μ2-H2O)5(H2O)40]·(ClO4)21·(H2O)100 (abbreviated as Ln37, Ln = Gd (1); Tb (2); Eu (3), LH3 = 1,2,3-cyclohexanetriol) and featuring a double cage-like structure, were obtained through the reaction of 1,2,3-cyclohexanetriol, acetate ligand, and Ln(ClO4)3. The largest odd-numbered lanthanide cluster Gd37 exhibits an entropy change (−ΔSm) of 38.7 J kg–1 K–1.
创建时间：
2017-02-06
