Delocalized Hypervalent Silyl Radical Supported by Amidinate and Imino Substituents
收藏NIAID Data Ecosystem2026-03-10 收录
下载链接：
https://figshare.com/articles/dataset/Delocalized_Hypervalent_Silyl_Radical_Supported_by_Amidinate_and_Imino_Substituents/4496000
下载链接
链接失效反馈官方服务：
资源简介：
The reaction of the
amidinato silylsilylene with a functionalized diaminochlorosilyl substituent,
[LSiSi(Cl){(NtBu)2C(H)Ph}] (1; L = PhC(NtBu)2), with ArNCNAr
(Ar = 2,6-iPr2C6H3) in toluene afforded the delocalized hypervalent silyl radical [LSi•(μ-CNAr)2Si{(NtBu)2C(H)Ph}] (2). It possesses a hypervalent silyl
radical that delocalizes throughout the Si2C2 ring.
创建时间：
2016-12-23
