Synthesis and Structure of Bis- and Tris-Benzyl Bismuth Complexes
收藏NIAID Data Ecosystem2026-03-07 收录
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The first crystallographic characterization of bismuth complexes containing benzyl ligands is reported. The NCN pincer ligand complex, Ar′BiCl2 [Ar′ = 2,6-(Me2NCH2)2C6H3], reacts with (PhCH2)MgCl to form Ar′Bi(η1-CH2Ph)2 in high yield. X-ray crystallography and spectroscopic studies confirm η1-bonding of the benzyl ligands in Ar′Bi(η1-CH2Ph)2 as well as in the homoleptic Bi(η1-CH2Ph)3.
创建时间：
2016-02-16
