Synthesis of β‑Amino Ketones by Addition of Aryl Methyl Ketones to Sulfinimines: Application to the Total Synthesis of HPA-12, Norsedamine, and Sedamine
收藏Figshare2017-11-30 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Amino_Ketones_by_Addition_of_Aryl_Methyl_Ketones_to_Sulfinimines_Application_to_the_Total_Synthesis_of_HPA-12_Norsedamine_and_Sedamine/5649634
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Synthesis of β-sulfinamido ketones was accomplished by the addition of silyl enol ethers derived from arylmethyl ketones to chiral sulfinimines in excellent yield and selectivity. Application of the formed β-amino substituted ketones is exemplified in the total synthesis of sphingolipid HPA-12 and the sedamine alkaloids.
创建时间：
2017-11-30
