Stepwise Hydrolysis of Aluminum Chloride Iodide LAlClI (L = HC[(CMe)(NAr)]<sub>2</sub>, Ar = 2,6-<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) in the Presence of <i>N</i>-Heterocyclic Carbene as Hydrogen Halide Acceptor<sup>†</sup>
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The aluminum chloride iodide LAlClI (2, L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) has been synthesized to study the stepwise hydrolysis of this compound in the presence of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene as hydrogen halide acceptor. The isolation and characterization of the aluminum chloride hydroxide [LAlCl(μ-OH)]2 (3) and the dihydroxide LAl(OH)2 (4) demonstrate the realization of a controlled hydrolysis.
创建时间：
2016-05-06
