Versatile Methods for Preparation of New Cyclometalated Gold(III) Complexes
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https://figshare.com/articles/dataset/Versatile_Methods_for_Preparation_of_New_Cyclometalated_Gold_III_Complexes/2484139
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资源简介：
Versatile methods for the high-yield syntheses of new
cyclometalated gold(III) complexes are described. Mono- or dialkylated
or arylated gold(III) complexes are selectively obtained from reaction
of Au(OCOCF3)2(tpy) (tpy = 2-(p-tolyl)pyridine) with either RMgX or RLi, respectively. Specifically,
AuMe2(tpy) and AuPh2(tpy) were prepared with
the respective lithium reagents, and AuBrMe(tpy), AuBrEt(tpy), and
AuBrPh(tpy) were prepared with Grignard reagents. The molecular structures
of compounds Au(OCOCF3)2(tpy) and AuMe2(tpy) were determined by single crystal X-ray diffraction.
创建时间：
2012-09-24
