Synthesis and Oligomerization of CpM(CO)<sub>2</sub>
收藏NIAID Data Ecosystem2026-03-13 收录
数据链接：
官方服务：
资源简介：
We showcase efficient synthetic protocols of cyclopentadienyl metal dicarbonyl, CpM(CO)2 (M = Rh and Ir). Reflecting the relativistic effect, the 1H and 13C signals of the Cp ring in CpIr(CO)2 were upfield shifted when compared with the Rh analogue. A missing dinuclear complex, (CpIr)2(μ-CO)(CO)2, was spontaneously generated together with [CpIr(CO)]3 by the loss of CO. The crystallographic analyses unambiguously determined their unique structures with one and three Ir–Ir bonds, respectively.
创建时间：
2021-11-24
