Pressure-Induced Internal Redox Reaction of Cs<sub>2</sub>[PdI<sub>4</sub>]·I<sub>2</sub>, Cs<sub>2</sub>[PdBr<sub>4</sub>]·I<sub>2</sub>, and Cs<sub>2</sub>[PdCl<sub>4</sub>]·I<sub>2</sub>
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The pressure-induced redox reaction within the system Cs2[Pd2+I4]·I2/Cs2[Pd4+I6] was investigated by means of powder X-ray diffraction. Analogous high-pressure X-ray diffraction experiments were performed on the isostructural compounds Cs2[PdX4]·I2 (X = Cl, Br). Additionally, the phase transition of Cs2[PdBr4]·I2 to Cs2[PdBr4I2] was characterized by means of Raman scattering experiments as well as theoretical calculations based on density functional theory. On the basis of experimentally determined crystal structure data, a pathway for the topology of the redox reactions was developed and outlined.
创建时间：
2006-11-27
