Synthesis of Neutral Mixed Sandwich CH2-SiR2 Bridged [2]Cobaltoarenophanes from the Dilithiation of Cb*CoCp [Co(η4-C4Me4)(η5-C5H5)]
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https://figshare.com/articles/dataset/Synthesis_of_Neutral_Mixed_Sandwich_CH_sub_2_sub_-SiR_sub_2_sub_Bridged_2_Cobaltoarenophanes_from_the_Dilithiation_of_Cb_CoCp_Co_sup_4_sup_-C_sub_4_sub_Me_sub_4_sub_sup_5_sup_-C_sub_5_sub_H_sub_5_sub_/12064851
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The dilithiation of [Co(η4-C4Me4)(η5-C5H5)] to give [Co(η4-C4Me3CH2Li)(η5-C5H4Li)]·PMDETA and the subsequent synthesis and characterization of the CH2-SiR2-bridged [2]cobaltoarenophanes is reported. This is the first development in the chemistry of neutral 18-electron metalloarenophanes featuring a group 9 transition metal.
创建时间:
2007-12-03



