Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of <i>C</i>‑Unsubstituted Au(I)–1,2,3-Triazole Carbene Complexes
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New and well-characterized Ag–bis(1,2,3-triazolylidene) complexes having enantiopure (S)-sulfoxides upon sequential treatment with alcohols and Au(I) form separable mixtures of regioisomeric C-unsubstituted Au–1,2,3-triazolylidene complexes. Mechanistic studies and DFT calculations support a desulfinylation process for in situ generated free triazolylidene salts.
创建时间：
2017-01-30
