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Selective Oxidations in the Synthesis of Complex Natural <i>ent</i>-Kauranes and <i>ent</i>-Beyeranes
收藏NIAID Data Ecosystem2026-03-13 收录
下载链接：
https://figshare.com/articles/dataset/Selective_Oxidations_in_the_Synthesis_of_Complex_Natural_i_ent_i_-Kauranes_and_i_ent_i_-Beyeranes/20349310
下载链接
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资源简介：
Syntheses of two natural products derived from the ent-kaurene kaurenoic acid are described for the first time
using regio-
and diastereoselective oxidations. Palladium- and manganese-mediated
oxidations were used to accomplish the syntheses of two ent-beyerane metabolites. The use of the White–Gormisky–Zhao
catalyst Mn(CF3-PDP) enabled the first application of a
nondirected metal-catalyzed oxidation in an unactivated C–H
bond in a total synthesis.
创建时间：
2022-07-21
