Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage
收藏NIAID Data Ecosystem2026-03-06 收录
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Aryl−iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl]2 and secondary phosphine oxide−oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C−P cleavage, was assigned by X-ray analysis and NMR spectroscopy.
创建时间：
2010-11-22
