Reaction Kinetics, Mechanisms and Catalysis(LYF)

Hydrazine borane (denoted as HB, N2H4BH3) has been recognized as an attractive hydrogen storage material owing to its high hydrogen capacity of 15.4 wt%. However, N2H4BH3 still faces challenges in thermolytic dehydrogenation, such as relatively high dehydrogenation temperatures and the generation of excessive by-products. In this study, we successfully introduced NiCl2 and CoCl2 into N2H4BH3 via a co-precipitation method, synthesizing a series of materials doped with different weight fractions of NiCl2 and CoCl2. Specifically, in the open system decomposit