A Cationic Guest in a 24<sup>+</sup> Cationic Host
收藏NIAID Data Ecosystem2026-03-06 收录
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A new tetrahedral coordination cage M12L6 was prepared from a linear dipyrimidine ligand (L) and cis-protected palladium(II) (M). This cage showed unprecedented host−guest chemistry where the cationic host accommodated a cationic guest despite 24+ charges on the host framework. The unusual cation−cation host−guest chemistry is described by a unique onionlike shell structure of the host−guest complex where two cationic spheres are mediated by an anionic sphere of a counteranion assembly.
创建时间：
2016-08-18
