Oxidative Degradation of Ethers Promoted by Strontium and Barium Tetraphenylimidodiphosphinates
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https://figshare.com/articles/dataset/Oxidative_Degradation_of_Ethers_Promoted_by_Strontium_and_Barium_Tetraphenylimidodiphosphinates/3264961
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资源简介:
The novel M[(OPPh2)2N]2·nTHF (M = Sr (2), Ba (3)) complexes
were prepared and characterized. Upon exposure to atmospheric
oxygen, 2 and 3 were transformed to the dinuclear species Sr2[(OPPh2)2N]4·2C3H6O3 (4) and Ba2[(OPPh2)2N]4·2C4H8O3 (5),
respectively. Compounds 4 and 5 contain coordinated carboxylic
acids obtained from the oxidative degradation of DME and THF,
respectively, which were used as solvents for crystallization.
创建时间:
2016-05-05



