Pesticides and Ozofractionation: An Investigation to Remove Organic and Inorganic Contaminants from Industrial Wastewater

In the last 50 years a significant amount of research
has been carried out on the treatment of pesticides and industrial wastewater using
physicochemical methods. However, ozofractionation has not been investigated as
a means to remove pesticides from wastewater, possibly because it is more
typically associated with the treatment of water in aquariums. Therefore, the present
study was undertaken to assess the impact of ozofractionation on pesticide-contaminated
industrial wastewater. A sample was collected from a stormwater holding tank at
a pesticide manufacturing site in Australia containing chlorpyrifos, dichlorodiphenyltrichloroethane
(DDT), dichlorodiphenyldichloroethylene (DDE), arsenic and zinc. After preliminary
analysis, the sample was subjected to ozofractionation and promising results
were observed. Chlorpyrifos, DDT, DDE, arsenic and zinc concentrations were 7.2
µg/L, 108 µg/L, 9.5 µg/L, 0.14 mg/L and 0.44 mg/L before treatment and reduced
to <0.5µg/L, <2.0 µg/L, <0.5 µg/L, 0.01 mg/L and <0.005 mg/L
respectively after treatment. Before treatment, pesticides and metal
concentrations were beyond discharge limits, however ozofractionation brought
them within the permissible limits set by environmental agencies and processed
wastewater could be discharged to an aquatic ecosystem. These findings indicate
that ozofractionation may be a useful method for destroying intractable pesticides
and removing heavy metals from industrial wastewater.