Reactive Intermediates from DMDO Oxidation of Ynamides. Trapping of a de novo Chiral Push−Pull Carbene via Cyclopropanation
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https://figshare.com/articles/dataset/Reactive_Intermediates_from_DMDO_Oxidation_of_Ynamides_Trapping_of_a_de_novo_Chiral_Push_Pull_Carbene_via_Cyclopropanation/2956231
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资源简介：
The reaction profile of DMDO oxidations of ynamides is described. This work illustrates the first examples of highly diastereoselective
intramolecular cyclopropanations of a push−pull carbene derived from alkyne oxidation. In addition, the ynamide oxidation provides facile
access to ketoimides and reveals mechanistic insights into the chemistry of electronically biased oxirenes.
创建时间：
2016-06-03
