Reactive Intermediates from DMDO Oxidation of Ynamides. Trapping of a de novo Chiral Push−Pull Carbene via Cyclopropanation
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The reaction profile of DMDO oxidations of ynamides is described. This work illustrates the first examples of highly diastereoselective intramolecular cyclopropanations of a push−pull carbene derived from alkyne oxidation. In addition, the ynamide oxidation provides facile access to ketoimides and reveals mechanistic insights into the chemistry of electronically biased oxirenes.
创建时间：
2016-06-03
