Enantioselective Synthesis of 4‑Heterosubstituted Cyclopentenones
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https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_4_Heterosubstituted_Cyclopentenones/2422579
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资源简介：
Racemic 4-hydroxycyclopentenone, readily derived from furfuryl alcohol, can be transformed via its O-Boc derivative to 4-acyloxy, 4-aryloxy-, 4-amino-, or 4-thio-substituted cyclopentenones with high enantioselectivity by palladium-catalyzed kinetic resolution via nucleophilic allylic substitutions. Applying this methodology, a short formal synthesis of ent-noraristeromycin was readily accomplished.
创建时间：
2016-02-19
