Reactivity of CuI and CuBr toward Dialkyl Sulfides RSR: From Discrete Molecular Cu4I4S4 and Cu8I8S6 Clusters to Luminescent Copper(I) Coordination Polymers
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资源简介：
The CuX salts (X = I, Br) react with SR2 to form molecular clusters of the types [(R2S)4(Cu4I4)] and [(R2S)6(Cu8I8)] or to give 1D polymers and 2D metal−organic frameworks. The cluster nuclearity and connectivity as well as the dimensionality of these compounds depend on the steric demand of SR2, the solvent polarity, and the nature of the halide. These materials have been characterized by X-ray and thermogravimetric analysis and steady-state and time-resolved absorption and emission spectroscopy at 298 and 77 K.
创建时间：
2018-07-17
