Halogen Bonding and π···π Stacking Control Reactivity in the Solid State
收藏NIAID Data Ecosystem2026-03-06 收录
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The halogen bonding and the π···π stacking interactions induce the noncovalent self-assembly of modules into photoreactive supramolecular architecture. The π···π interaction pre-organizes the template, and the halogen bonding aligns the olefins to conform to the topochemical principle for photoreaction. The UV irradiation of the crystal resulted in a cyclization product with quantitative yield and stereospecificity.
创建时间：
2016-05-07
