five

Synthesis and Structure of Group 4 and 5 Metal Complexes with an Ancillary Sterically Demanding Diamido Ligand

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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Group_4_and_5_Metal_Complexes_with_an_Ancillary_Sterically_Demanding_Diamido_Ligand/3786150
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资源简介:
Reaction of tetrachlorides of group 4 and 5 transition metals with the chelating diamide [Me2C(CH2N(Li)(SiButPh2))2] (LLi2) leads to LMCl2 (M = Ti, Zr, Hf, V) complexes, which were characterized by X-ray diffraction. The reactivity of LMCl2 toward ethylene polymerization was tested with MAO as cocatalyst.
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2016-08-27
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