Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex
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https://figshare.com/articles/dataset/Structure_Reactivity_and_Computational_Studies_of_a_Novel_Ruthenium_Hydrogen_Sulfide_Dihydride_Complex/3358015
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资源简介：
Addition of 1 atm of H2S to [Ru(IMes)2(CO)(EtOH)H2] (IMes =
1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)(H2S)H2] 2. Treatment of 2 with excess H2S leads to formation of
the 16-electron bis-hydrosulfido complex, [Ru(IMes)2(CO)(SH)2] 3.
Preliminary studies show that 3 reacts with both H2 and CO in
solution as well as in the solid state. Both 2 and 3 have been
structurally characterized
创建时间：
2003-12-01
