Regio- and Enantioselective Baeyer–Villiger Oxidation: Kinetic Resolution of Racemic 2‑Substituted Cyclopentanones
收藏NIAID Data Ecosystem2026-03-08 收录
数据链接：
官方服务：
资源简介：
A kinetic resolution of racemic 2-substituted cyclopentanones via highly regio- and enantioselective Baeyer–Villiger oxidation has been successfully developed. The reaction could afford the normal 6-substituted δ-lactones in up to 98% ee and >19/1 regioselectivity. Meanwhile, the unreacted ketones were recovered in excellent ee values (up to 98%). It represents the best results of the kinetic resolution of racemic 2-substituted cyclopentanones via nonenzymic asymmetric BV oxidation.
创建时间：
2016-02-17
