Ferroelectric Switchable Behavior through Fast Reversible De/adsorption of Water Spirals in a Chiral 3D Metal–Organic Framework
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https://figshare.com/articles/dataset/Ferroelectric_Switchable_Behavior_through_Fast_Reversible_De_adsorption_of_Water_Spirals_in_a_Chiral_3D_Metal_Organic_Framework/2395528
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资源简介：
A polar
homochiral 3D MOF [{Co2(L)(bpe)(H2O)}·5H2O]n constructed
with cobalt(II) and a new ligand N-(1,3-dicarboxy-5-benzyl)-carboxymethylglycine
(H4L) accommodates ordered helical water streams in its
helical grooves. It provides the first example of switchable ferroelectric
and optical behavior through two-step reversible single-crystal to
single-crystal transformation (SCSC) upon desorption/adsorption of
water spirals and coordinated water molecules, respectively.
创建时间：
2016-02-19
