Direct Synthesis of Substituted Naphthalenes from 1,3-Dicarbonyl Compounds and 1,2-Bis(halomethyl)benzenes Including a Novel Rearrangement Aromatization of Benzo[c]oxepine
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https://figshare.com/articles/dataset/Direct_Synthesis_of_Substituted_Naphthalenes_from_1_3_Dicarbonyl_Compounds_and_1_2_Bis_halomethyl_benzenes_Including_a_Novel_Rearrangement_Aromatization_of_Benzo_i_c_i_oxepine/2462698
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An unexpected rearrangement aromatization of benzo[c]oxepine has been revealed to synthesize substituted naphthalenes. This observation was further exploited to develop an efficient approach for the construction of naphthalenes from simple and commercially available 1,3-dicarbonyl compounds and 1,2-bis(halomethyl)benzene compounds via a new domino reaction sequence.
创建时间:
2016-02-20



