SmI<sub>2</sub>-Mediated Radical Cyclizations Directed by a C−Si Bond
收藏NIAID Data Ecosystem2026-03-06 收录
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The use of a silicon stereocontrol element in cyclobutanol and cyclopentanol-forming cyclizations mediated by SmI2 results in excellent diastereocontrol. The C−Si bond in the products of cyclization provides a versatile handle for further manipulation. An asymmetric route to cyclization substrates involving copper-catalyzed silyl transfer has also been developed.
创建时间：
2016-02-24
