Reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Me3SiC⋮CR. Synthesis and Structural Characterization of Mononuclear Ruthenium Bis(vinylidene) and Vinylvinylidene Complexes

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数据链接：

https://figshare.com/articles/dataset/Reaction_of_sup_5_sup_Me_sub_2_sub_C_C_sub_5_sub_H_sub_4_sub_C_sub_2_sub_B_sub_10_sub_H_sub_10_sub_Ru_NCCH_sub_3_sub_sub_2_sub_with_Me_sub_3_sub_SiC_CR_Synthesis_and_Structural_Characterization_of_Mononuclear_Ruthenium_Bis_vinylidene_and_Vinylvinylidene_C/3221527 数据链接链接失效反馈

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资源简介：

The substituent R plays a crucial role in the reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Me3SiC⋮CR. If R = Me3Si, this reaction led to the isolation of the first mononuclear bis(vinylidene)metal complex. If R = H, a vinylvinylidenemetal complex was generated.

创建时间：

2016-05-05

Reaction of [η<sup>5</sup>:σ-Me<sub>2</sub>C(C<sub>5</sub>H<sub>4</sub>)(C<sub>2</sub>B<sub>10</sub>H<sub>10</sub>)]Ru(NCCH<sub>3</sub>)<sub>2</sub> with Me<sub>3</sub>SiC⋮CR. Synthesis and Structural Characterization of Mononuclear Ruthenium Bis(vinylidene) and Vinylvinylidene Complexes

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