Enantioselective β‑Boration of Acyclic Enones by a [2.2]Paracyclophane-Based N‑Heterocyclic Carbene Copper(I) Catalyst
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https://figshare.com/articles/dataset/Enantioselective_Boration_of_Acyclic_Enones_by_a_2_2_Paracyclophane_Based_N_Heterocyclic_Carbene_Copper_I_Catalyst/2442805
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资源简介：
A new planar and centrally chiral bicyclic 1,2,4-triazolium
salt
has been synthesized from [2.2]paracyclophane and phenylglycinol.
The N-heterocyclic carbene (NHC) copper(I) complex generated in situ
by the reaction of the triazolium salt and Cu2O was an
efficient catalyst for the asymmetric β-boration of acyclic
enones, producing β-boryl ketones in high yields and enantioselectivities.
创建时间：
2013-02-15
