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Field Supported Slow Magnetic Relaxation in a Mononuclear Cu(II) Complex

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Field_Supported_Slow_Magnetic_Relaxation_in_a_Mononuclear_Cu_II_Complex/4533020
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A mononuclear hexacoordinate Cu­(II) complex shows a field induced slow magnetic relaxation that is not facilitated by an energy barrier to spin reversal due to the zero-field splitting. Two relaxation channels were found: the magnetic field strongly supports the low-frequency relaxation path with a relaxation time as long as τ = 0.8 s at T = 1.9 K and B = 1.5 T. The mechanism of the relaxation at low temperature involves the dominant Raman process for this S = 1/2 spin system along with a temperature-independent term belonging to a quantum tunneling.
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2017-01-09
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