Uncommon η<sup>3</sup>-(<i>N</i>,<i>C</i>,<i>C</i>‘)-1-Azaallyl Bonding Mode for the Nacnac Ligand: A Bis(β-diketiminato)uranium(III) Iodide Complex
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资源简介：
The reaction between 2 equiv of K(Nacnac) (Nacnac- = [Ar]NC(Me)CHC(Me)N[Ar], Ar = 2,6-iPr2C6H3) and UI3(THF)4 in toluene affords (Nacnac)2UI (4), which features a β-diketiminate ligand bound to uranium(III) in an unusual η3-(N,C,C‘)-1-azaallyl mode and possesses close U···Calkene contacts.
创建时间：
2004-10-11
