Phosphorus Phenyl-Group Activation by Reduced Zirconium and Niobium Complexes Stabilized by the [P<sub>2</sub>N<sub>2</sub>] Macrocycle
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
Reduction of [P2N2]ZrCl2 (where [P2N2] = PhP(CH2SiMe2NSiMe2CH2)2PPh) with KC8 under argon generates the phosphorus phenyl bridged bimetallic complex where the bridging phenyl groups are formally reduced to bis(allyl) dianions. Similar reduction of [P2N2]NbCl caused the one-electron reduction of the phosphorus phenyl group to generate a cyclohexadienyl moiety via a C−C bond formation between the ipso carbons of the two phenyl groups.
创建时间：
2016-08-18
