Switching between Novel Samarium(II)-Mediated Cyclizations by a Simple Change in Alcohol Cosolvent
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
γ,δ-Unsaturated ketones undergo two very different stereoselective cyclization reactions mediated by samarium(II) iodide depending upon the alcohol cosolvent used in the reaction. Switching between an unprecedented aldol spirocyclization and a novel cyclobutanol-forming process can be achieved simply by changing the alcohol cosolvent from methanol to tert-butyl alcohol.
创建时间：
2016-05-07
