Catalytic Reduction of Hydrazine to Ammonia by a Vanadium Thiolate Complex
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下载链接:
https://figshare.com/articles/dataset/Catalytic_Reduction_of_Hydrazine_to_Ammonia_by_a_Vanadium_Thiolate_Complex/3227092
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资源简介:
Vanadium(III) thiolate complexes, [V(PS3‘ ‘)(Cl)]- [1a; PS3‘ ‘ =
P(C6H3-3-Me3Si-2-S)33-] and [V(PS3‘)(Cl)]- [1b; PS3‘ = P(C6H3-5-Me-2-S)33-], were synthesized and characterized. Complex 1a
serves as a precursor for the catalytic reduction of hydrazine to
ammonia. The spectroscopic and electrochemical studies indicate
that hydrazine is bound and activated in a VII state.
创建时间:
2016-05-05



