In-situ Electron Paramagnetic Resonance Investigation of Isotope-selective Breathing in MIL-53 during Dihydrogen Adsorption

Description of the dataset:

Data type: Experimental spectroscopic measurements including CW EPR, Pulsed EPR raw data, N2 isotherm, CO2 isotherm and crystal structure data

Files are with filename extensions: spc, par, dta, dsc, aif, csv, cif, txt and opj

Information on origin of the data:

EPR spectroscopic measurements with filename extensions spc, par dta, dsc, txt and opj.

Data visualisation was conducted using OriginLab version 8 and Microsoft Power Point.

X-band CW-EPR spectroscopic measurements data were generated by EMX spectrometer equipped with SHQ cavity produced by Bruker.

Pulsed X-band EPR measurements data were generated by Bruker ELEXYS E580 spectrometer.

Additional Information :

specialized abbreviations: EPR – Electron Paramagnetic Resonance, MIL – Matériaux de l’Institut Lavoisier

definitions of variables: Magnetic field, Pressures, Microwave power.

units of measurement: Gauss (G), milliTesla (mT), millibar(mbar), microwave power (dB).

abbreviations on the CW-EPR data filename: Dates, Sample name,  H2/D2 ads/des (ads= adsorption, des=desorption), microwave power, D2 or H2 pressures, number scans if indicated.

abbreviations on the pulsed EPR data filename: Dates, Sample name,  H2/D2 ads/des (ads= adsorption, des=desorption), D2 or H2 pressures, pulse sequences, pulse delay, temperature.