Stereoselective and Efficient Total Synthesis of Optically Active Tetrodotoxin from d-Glucose
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https://figshare.com/articles/dataset/Stereoselective_and_Efficient_Total_Synthesis_of_Optically_Active_Tetrodotoxin_from_d_Glucose/2957032
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资源简介：
A stereoselective and efficient total synthesis of optically active tetrodotoxin (TTX) is described. A
polyfunctionalized key cyclitol compound containing branched-chains for the synthesis of TTX was
prepared from d-glucose employing the Henry reaction (Nitro aldol reaction) as the key transformation.
Stereoselective construction of the α-azido-aldehyde branched-chain was achieved via the key spiro
α-chloroepoxide intermediate.
创建时间：
2016-06-03
