Reactivity of a Pd(I)−Pd(I) Dimer with O<sub>2</sub>: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium
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The Pd(I)−Pd(I) dimer [(FPNP)Pd−]2 reacts with O2 upon exposure to light to produce either the superoxide (FPNP)PdO2 or the peroxide [(FPNP)PdO−]2, which exist in equilibrium with free O2. Both complexes contain square-planar Pd(II) centers. The unpaired electron density in (FPNP)PdO2 is localized on the superoxide ligand.
创建时间：
2011-03-23
