Ligand labilization gates intramolecular electron transfer in molecular photocatalyst - dataset

The Dataset represents a collection of pump-pulse femtosecond transient absorption spectroscopy data to investigate the effect of temperature and the excess of chloride to the photoinduced reduction of the rhodium center in the supramolecular photocatalytic precursor [(tbbpy)2Ru(tpphz)Rh(Cp*)Cl]Cl(PF6)2 by the change of the corresponding time constant τ3. The Dataset consist of the experimental raw data, Phyton Notebooks which were used to process this data with the help of the Python Package "KiMoPack", as well as excel and origin sheets to analyze the processed data. The valdility of the collected data in regards of the photostability of the sample is supported by the steady-state UV-vis spectra before and after the pump-probe experiments.